Kym plays Donna Sanderson in the Kay Mellor drama, which follows a group of dog kennel workers, who may have won the lottery.
The programme also stars Neil Morrissey, Gaynor Faye and Strictly’s Joe Sugg.
The actress said she enjoyed her role in the show as it was “so different” to her character in Coronation Street.
However, unluckily for Kym, her character did not get to go to Monaco to shoot scenes with the rest of the cast.
The Syndicate airs on Tuesday at 9pm on BBC One.